Material Safety Data Sheet
K-GRIP 392
Maple Leaf Sales II, inc.
Middleville, Michigan
Emergency Number: 1-800-424-9300
(Chemtrec)
MLS Number: MLS 660601
MSDS Revision Date:
Section 1 Product Identification
K-GRIP 392
One Part Water Based Spray Adhesive
Section 2 Composition, Information on Ingredients
1.
Ammonia CAS#
7664-41-7 % by
Weight: <1 Exposure
Limit: ACGIH
TLV-TWA: 25 ppm ACGIH
TLV-STEL: 35 ppm OSHA
PEL-TWA: 50 ppm NIOSH
REL-TWA: 25 ppm NIOSH
REL-STEL: 35 ppm 2.
Potassium Hydroxide CAS#
1310-58-3 % by
Weight: <1 Exposure
Limit: ACGIH
TLV-CEILING: 2 mg/cum OSHA
PEL-TWA: N/D NIOSH
REL-TWA: 2 mg/cum |
3.
Zinc Oxide CAS#
1314-13-2 Aliphatic
Petroleum Distillates % by
Weight: 1 - 5 Exposure
Limit: ACGIH
TLV-TWA: 10 mg/cum OSHA
PEL-TWA: 15 mg/cum Total dust, 5 mg/cum Respirable dust NIOSH
REL-TWA: 5 mg/cum NIOSH
REL-CEILING: 15 mg/cum, 15 min. TWA |
HMIS Information:
Health: 1, Flammability: 0, Reactivity: 0
Hazard
Rating: 0 Minimal 1 Slight 2 Moderate 3 High 4 Extreme * Chronic
**This product contains no
reportable carcinogens or suspected carcinogens.**
Section 3 Hazards Identification
Emergency Overview:
Potential Health Effects:
For short term overexposure
Eye:
Can cause irritation.
Symptoms may include stinging, burning, tearing, and redness.
Skin:
Prolonged or repeated contact may cause irritation and dry
the skin. Symptoms may include redness,
burning, drying and cracking of skin.
Inhalation:
Inhalation of vapor or mist may cause irritation of nose,
throat, airways, runny nose, cough, and possibly chest pains.
Ingestion:
Can cause irritation of the mouth, throat, and
gastrointestinal tract. Symptoms may include
abdominal pain, nausea, vomiting. The
latex portion of product will coagulate (solidify) in the digestive tract.
Target Organ / Chronic Effects:
For repeated overexposure
This product may contain small amounts of volatile organic
compounds. During storage and
processing (application, drying, curing), small amounts of organic volatiles
may be released. No significant amount
of exposure is anticipated when good industrial hygiene practices are observed.
Prolonged exposure to ammonia vapors could cause bronchitis
and pneumonia. Prolonged contact with
substances containing ammonia can cause irritation and chemical burns.
Prolonged exposure to ammonia vapors could cause bronchitis
and pneumonia. Prolonged contact with
substances containing ammonia can cause irritation and chemical burns.
Prolonged contact with substances containing potassium
hydroxide can cause irritation and chemical burns.
Inhalation of high levels of zinc oxide dust may result in
tightness of chest, metallic taste, cough, dizziness, fever, chills, headache,
nausea, and dry throat.
This product contains natural latex rubber. An FDA Medical Alert has been issued (March
29, 1991: MDA 91-1) concerning Allergic Reactions to Latex-Containing Medical
Devices. This alert states that medical
devices manufactured from natural latex rubber have been reported to cause
allergic reactions, including anaphylaxis, in some individuals. NIOSH Alert (No. 97-135, June 1997): Workers
exposed to latex gloves and other products containing natural rubber latex may
develop allergic reactions such as skin rashes; hives; nasal, eye, or sinus
symptoms; asthma; and (rarely) shock.
Carcinogenicity:
Based on the available information, this product is not
expected to be carcinogenic in humans.
This product contains no components in quantities greater than or equal
to 0.1% by weight that are listed as proven or suspect carcinogens by IARC,
NTP, or OSHA
Primary Route(s) of Entry:
Inhalation, eye contact, skin contact
Section 4 First Aid Measures
Eye Contact:
Flush eyes gently with plenty of water. Get medical attention if irritation
persists.
Skin Contact:
Inhalation:
Remove individual to fresh air. If breathing is difficult, administer oxygen. Seek medical attention.
Ingestion:
Dilute stomach contents with water. Do not induce vomiting. Seek medical attention.
Note to Physician:
Any treatment that might be required for overexposure should
be directed at the control of symptoms and the clinical condition.
Section 5 Fire Fighting Measures
Fire and Explosive Properties of the Chemical:
No unusual fire or explosion hazards.
Product will not burn but may spatter if the temperature
exceeds the boiling point of water.
The solids portion of the product is combustible and will
decompose during combustion or under pyrolysis conditions giving off toxic
fumes.
Closed containers may rupture if exposed to extreme heat or
fire.
Flammability Classification: N/A DOT: N/A
Flashpoint: None: N/A
Flammable / Explosive Limits:
Lower: N/A Volume in Air
Upper: N/A Volume in Air
Auto-ignition Temperature: N/A
Extinguishing Media:
Same as for surrounding fire. Liquid material is not flammable. Water, foam, carbon dioxide, and dry chemical are suitable for
use on dry solids fire.
Fire-Fighting Procedures and Equipments:
Wear a self-contained breathing apparatus when fighting
fires. Water may be used to keep
fire-exposed containers cool until fire is out.
Section 6 Accidental Release Measures
Containment and Clean-Up:
Stop spill at source.
Contain spilled liquid with sand, earth, vermiculite or other inert
absorbent material. Prevent spill from
contaminating soil or from entering sewage and drainage systems, and other
bodies of water.
Persons not wearing protective equipment should be excluded
from area of spill until clean-up has been completed. If recovery is feasible, transfer to clean container by suction
or other suitable means. If recovery is
not feasible, admix with inert absorbent material and place in appropriately
marked chemical waste container for disposal.
Flush spill area with water spray.
Section 7 Handling and Storage
Handling:
Handle with reasonable care. Avoid breathing spray mist.
Avoid repeated or prolonged breathing of vapors. Avoid eye contact and repeated or prolonged
skin contact. When opening containers,
remove top slowly to relieve any pressure build-up. Do not transfer product to unmarked container. Keep out of the reach of children. For industrial use only.
Containers of this material may be hazardous when
emptied. Because emptied containers
retain product residues (vapor, liquid and/or solid), all hazard precautions
given in the data sheet must be observed.
Any proposed use of this product in elevated temperature
processes or in spray applications should be thoroughly evaluated to assure
that safe operating conditions are established and maintained.
Storage:
Keep product containers cool, dry, and away from sources of
ignition. Use and store this product
with adequate ventilation. Keep product
containers tightly closed when not in use.
Avoid freezing temperatures during storage.
Minimize contact with atmospheric air to prevent inoculation
with microorganisms which can cause decomposition and moldy overgrowth. If headspace ventilation is required, use
humidified air to reduce skin formation on emulsion surface.
Special Comments:
Practice safe working procedures and good personal
hygiene. Use protective equipment when
necessary. Wash thoroughly after
handling and before eating, drinking, smoking, or using toilet facilities.
Section 8 Exposure Controls, Personal
Protection
Eye Protection:
Chemical splash goggles are advised. Consult with safety representative. Readily accessible eyewash stations and
safety showers in work areas are recommended.
Skin Protection:
The use of chemical resistant gloves is recommended (consult
with safety equipment supplier). If
necessary, wear impervious clothing and boots.
Respiratory Protection:
Not required under normal conditions of use in a well
ventilated workplace.
Engineering Controls:
General mechanical ventilation and/or local exhaust
recommended.
Section 9 Physical and Chemical
Properties
Color: Off-White pH: 9.5 (+/- 1.0) Vapor Pressure: 17.00 mmHg @ 68° F Vapor Density: .62 Air = 1 Boiling Range: Lower:
212.0° F Higher:
N/A Water Solubility: Water dispersible Specific Gravity: 1.063 |
Density: 8.8507 Lb/Gal. Evaporation Rate: .200 (n-Butyl Acetate = 1) Volatile (% Weight): 46.6193 Volatile (% Volume): 49.5703 VOC (% Weight): .0004 VOC (% Volume): .0000 VOC (Less water and exempt solvent): .000 Lb/Gal. VOC (Less water and exempt solvent): .00 GM/L Static Electricity Explosion: N/A |
Section 10 Stability and Reactivity
Incompatibilities:
Avoid contact with:
Strong acids (mineral acids)
Strong bases (alkalies, caustics)
Strong oxidizing agents
Water sensitive materials
Decomposition:
Hazardous combustion and decomposition products:
Carbon monoxide and carbon dioxide
Ammonia, hydrogen chloride
Other unidentified organic compounds and toxic substances
Conditions to Avoid:
Coagulation may occur following freezing, thawing, boiling,
or the addition of chemicals.
Polymerization:
Product will not undergo hazardous polymerization.
Stability:
Stable under normal conditions of temperature and pressure.
Section 11 Toxicological Information
No data for product.
Section 12 Ecological Information
Ecotoxicological Information:
Aquatic Toxicity: No information is available for product.
Do Not Discharge to Streams, Lakes, Ponds or Sewers.
Environmental Fate:
No data for product
Section 13 Disposal Considerations
Waste Disposal:
Do not flush to sewer.
Dispose of in accordance with all applicable federal, state or
provincial, and local laws and regulations.
Disposal through licensed waste disposal facilities is suggested.
Section 14 Transport Information
**This product is not regulated by DOT**
Section 15 Regulatory Information
Federal Regulations:
TSCA (
The intentional ingredients of this product are listed.
SARA 313 Information:
This product contains the following substances subject to the
reporting requirements of Section 313 of Title III of the Superfund Amendments
and Reauthorization Act of 1986 and 40 CFR Part 372.
Zinc oxide
CAS# 1314-13-2
% by Weight: 1 - 5
State Regulations:
No data available for product
International Regulations:
No data available for product
Section 16 Other Information
Disclaimer of Warranty and Other Comments:
This document has been prepared in accordance with the
requirements of the OSHA Hazard Communication Standard 29 CFR 1910.1200. The information contained herein is, to the
best of our knowledge and belief, accurate.
However, because the conditions of handling and use are beyond our
control, we make no guarantee of results, and assume no liability for damages
incurred by the use of this material. It
is the responsibility of the user to comply with all federal, state, and local
laws and regulations.
The responsibility to provide a safe workplace remains with
the user. The user should consider the
health hazards and safety information contained herein as a guide and should
take those precautions required in an individual operation to instruct
employees and to develop work practice procedures for a safe work environment.
Abbreviations:
ACGIH: American Conference of Governmental &
Industrial Hygienists. OSHA: Occupational Safety & Health Administration NIOSH: National Institute for Occupational Safety and
Health IARC: International Agency for Research on Cancer NTP: National Toxicology Program TLV: Threshold Limit Value (ACGIH) PEL: Permissible Exposure Limit (OSHA) |
TWA: Time Weighted Average STEL: Short Term Exposure Limit ppm:
parts per million mg/cum:
milligrams per cubic meter of air N/D: Not
Determined N/A: Not
Applicable HMIS: Hazardous Materials Identification System |