Material Safety Data Sheet

K-GRIP 392

 

Maple Leaf Sales II, inc.

Middleville, Michigan

 

Emergency Number: 1-800-424-9300 (Chemtrec)

MLS Number: MLS 660601

MSDS Revision Date: 1/17/2001

 

Section 1 – Product Identification

K-GRIP 392 One Part Water Based Spray Adhesive

 

 

Section 2 – Composition, Information on Ingredients

1. Ammonia

CAS# 7664-41-7

% by Weight: <1

Exposure Limit:

ACGIH TLV-TWA: 25 ppm

ACGIH TLV-STEL: 35 ppm

OSHA PEL-TWA: 50 ppm

NIOSH REL-TWA: 25 ppm

NIOSH REL-STEL: 35 ppm

 

2. Potassium Hydroxide

CAS# 1310-58-3

% by Weight: <1

Exposure Limit:

ACGIH TLV-CEILING: 2 mg/cum

OSHA PEL-TWA: N/D

NIOSH REL-TWA: 2 mg/cum

3. Zinc Oxide

CAS# 1314-13-2

Aliphatic Petroleum Distillates

% by Weight: 1 - 5

Exposure Limit:

ACGIH TLV-TWA: 10 mg/cum

OSHA PEL-TWA: 15 mg/cum Total dust, 5 mg/cum Respirable dust

NIOSH REL-TWA: 5 mg/cum

NIOSH REL-CEILING: 15 mg/cum, 15 min. TWA

 

HMIS Information:

Health: 1, Flammability: 0, Reactivity: 0

Hazard Rating: 0 – Minimal   1 – Slight   2 – Moderate    3 – High    4 – Extreme   * – Chronic

 

**This product contains no reportable carcinogens or suspected carcinogens.**

 

 

Section 3 – Hazards Identification

Emergency Overview:

Mobile to viscous liquid with an ammonia odor.  Can cause eye, skin and respiratory tract irritation.  May be harmful if swallowed.  Product will burn only after the water it contains is driven off.

Potential Health Effects:

For short term overexposure

Eye:

Can cause irritation.  Symptoms may include stinging, burning, tearing, and redness.

Skin:

Prolonged or repeated contact may cause irritation and dry the skin.  Symptoms may include redness, burning, drying and cracking of skin.

Inhalation:

Inhalation of vapor or mist may cause irritation of nose, throat, airways, runny nose, cough, and possibly chest pains.

Ingestion:

Can cause irritation of the mouth, throat, and gastrointestinal tract.  Symptoms may include abdominal pain, nausea, vomiting.  The latex portion of product will coagulate (solidify) in the digestive tract. 

Target Organ / Chronic Effects:

For repeated overexposure

This product may contain small amounts of volatile organic compounds.  During storage and processing (application, drying, curing), small amounts of organic volatiles may be released.  No significant amount of exposure is anticipated when good industrial hygiene practices are observed.

Prolonged exposure to ammonia vapors could cause bronchitis and pneumonia.  Prolonged contact with substances containing ammonia can cause irritation and chemical burns.

Prolonged exposure to ammonia vapors could cause bronchitis and pneumonia.  Prolonged contact with substances containing ammonia can cause irritation and chemical burns.

Prolonged contact with substances containing potassium hydroxide can cause irritation and chemical burns.

Inhalation of high levels of zinc oxide dust may result in tightness of chest, metallic taste, cough, dizziness, fever, chills, headache, nausea, and dry throat.

This product contains natural latex rubber.  An FDA Medical Alert has been issued (March 29, 1991: MDA 91-1) concerning “Allergic Reactions to Latex-Containing Medical Devices”.  This alert states that medical devices manufactured from natural latex rubber have been reported to cause allergic reactions, including anaphylaxis, in some individuals.  NIOSH Alert (No. 97-135, June 1997): Workers exposed to latex gloves and other products containing natural rubber latex may develop allergic reactions such as skin rashes; hives; nasal, eye, or sinus symptoms; asthma; and (rarely) shock.

Carcinogenicity:

Based on the available information, this product is not expected to be carcinogenic in humans.  This product contains no components in quantities greater than or equal to 0.1% by weight that are listed as proven or suspect carcinogens by IARC, NTP, or OSHA

Primary Route(s) of Entry:

Inhalation, eye contact, skin contact

 

 

Section 4 – First Aid Measures

Eye Contact:

Flush eyes gently with plenty of water.  Get medical attention if irritation persists.

Skin Contact:

Wash exposed skin area with soap and water.  Consult physician if irritation persists.  Launder contaminated clothing before reuse.

Inhalation:

Remove individual to fresh air.  If breathing is difficult, administer oxygen.  Seek medical attention.

Ingestion:

Dilute stomach contents with water.  Do not induce vomiting.  Seek medical attention.

Note to Physician:

Any treatment that might be required for overexposure should be directed at the control of symptoms and the clinical condition.

 

 

Section 5 – Fire Fighting Measures

Fire and Explosive Properties of the Chemical:

No unusual fire or explosion hazards.

Product will not burn but may spatter if the temperature exceeds the boiling point of water.

The solids portion of the product is combustible and will decompose during combustion or under pyrolysis conditions giving off toxic fumes.

Closed containers may rupture if exposed to extreme heat or fire.

Flammability Classification: N/A              DOT: N/A

Flashpoint: None: N/A

Flammable / Explosive Limits:

Lower: N/A Volume in Air

Upper: N/A Volume in Air

Auto-ignition Temperature: N/A

Extinguishing Media:

Same as for surrounding fire.  Liquid material is not flammable.  Water, foam, carbon dioxide, and dry chemical are suitable for use on dry solids fire.

Fire-Fighting Procedures and Equipments:

Wear a self-contained breathing apparatus when fighting fires.  Water may be used to keep fire-exposed containers cool until fire is out.

 

 

Section 6 – Accidental Release Measures

Containment and Clean-Up:

Stop spill at source.  Contain spilled liquid with sand, earth, vermiculite or other inert absorbent material.  Prevent spill from contaminating soil or from entering sewage and drainage systems, and other bodies of water.

Persons not wearing protective equipment should be excluded from area of spill until clean-up has been completed.  If recovery is feasible, transfer to clean container by suction or other suitable means.  If recovery is not feasible, admix with inert absorbent material and place in appropriately marked chemical waste container for disposal.

Flush spill area with water spray.  Wash contaminated property before the material dries.  Spilled product is very slippery.  Use care to avoid falls.  A film will form on drying.

 

 

Section 7 – Handling and Storage

Handling:

Handle with reasonable care.  Avoid breathing spray mist.  Avoid repeated or prolonged breathing of vapors.  Avoid eye contact and repeated or prolonged skin contact.  When opening containers, remove top slowly to relieve any pressure build-up.  Do not transfer product to unmarked container.  Keep out of the reach of children.  For industrial use only.

Containers of this material may be hazardous when emptied.  Because emptied containers retain product residues (vapor, liquid and/or solid), all hazard precautions given in the data sheet must be observed. 

Any proposed use of this product in elevated temperature processes or in spray applications should be thoroughly evaluated to assure that safe operating conditions are established and maintained.

Storage:

Keep product containers cool, dry, and away from sources of ignition.  Use and store this product with adequate ventilation.  Keep product containers tightly closed when not in use.  Avoid freezing temperatures during storage.

Minimize contact with atmospheric air to prevent inoculation with microorganisms which can cause decomposition and moldy overgrowth.  If headspace ventilation is required, use humidified air to reduce skin formation on emulsion surface.

Special Comments:

Practice safe working procedures and good personal hygiene.  Use protective equipment when necessary.  Wash thoroughly after handling and before eating, drinking, smoking, or using toilet facilities.

 

 

Section 8 – Exposure Controls, Personal Protection

Eye Protection:

Chemical splash goggles are advised.  Consult with safety representative.  Readily accessible eyewash stations and safety showers in work areas are recommended.

Skin Protection:

The use of chemical resistant gloves is recommended (consult with safety equipment supplier).  If necessary, wear impervious clothing and boots.

Respiratory Protection:

Not required under normal conditions of use in a well ventilated workplace.

Engineering Controls:

General mechanical ventilation and/or local exhaust recommended.

 

 

Section 9 – Physical and Chemical Properties

Physical State: Liquid

Color: Off-White

pH: 9.5 (+/- 1.0)

Vapor Pressure: 17.00 mmHg @ 68° F

Vapor Density: .62 Air = 1

Boiling Range:

            Lower: 212.0° F

            Higher: N/A

Water Solubility: Water dispersible

Specific Gravity: 1.063

Density: 8.8507 Lb/Gal.

Evaporation Rate: .200 (n-Butyl Acetate = 1)

Volatile (% Weight): 46.6193

Volatile (% Volume): 49.5703

VOC (% Weight): .0004

VOC (% Volume): .0000

VOC (Less water and exempt solvent): .000 Lb/Gal.

VOC (Less water and exempt solvent): .00 GM/L

Static Electricity Explosion: N/A

Section 10 – Stability and Reactivity

Incompatibilities:

Avoid contact with:

Strong acids (mineral acids)

Strong bases (alkalies, caustics)

Strong oxidizing agents

Water sensitive materials

Decomposition:

Hazardous combustion and decomposition products:

Carbon monoxide and carbon dioxide

Ammonia, hydrogen chloride

Other unidentified organic compounds and toxic substances

Conditions to Avoid:

Coagulation may occur following freezing, thawing, boiling, or the addition of chemicals.

Polymerization:

Product will not undergo hazardous polymerization.

Stability:

Stable under normal conditions of temperature and pressure.

 

 

Section 11 – Toxicological Information

No data for product.

 

 

Section 12 – Ecological Information

Ecotoxicological Information:

Aquatic Toxicity: No information is available for product.

Do Not Discharge to Streams, Lakes, Ponds or Sewers.

Environmental Fate:

No data for product

 

 

Section 13 – Disposal Considerations

Waste Disposal:

Do not flush to sewer.  Dispose of in accordance with all applicable federal, state or provincial, and local laws and regulations.  Disposal through licensed waste disposal facilities is suggested.

 

 

Section 14 – Transport Information

**This product is not regulated by DOT**

 

 

Section 15 – Regulatory Information

Federal Regulations:

TSCA (U.S. Toxic Substances Control Act) Status:

The intentional ingredients of this product are listed.

SARA 313 Information:

This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372.

Zinc oxide

CAS# 1314-13-2

% by Weight: 1 - 5

State Regulations:

No data available for product

International Regulations:

No data available for product

 

 

Section 16 – Other Information

Disclaimer of Warranty and Other Comments:

This document has been prepared in accordance with the requirements of the OSHA Hazard Communication Standard 29 CFR 1910.1200.  The information contained herein is, to the best of our knowledge and belief, accurate.  However, because the conditions of handling and use are beyond our control, we make no guarantee of results, and assume no liability for damages incurred by the use of this material.  It is the responsibility of the user to comply with all federal, state, and local laws and regulations.

The responsibility to provide a safe workplace remains with the user.  The user should consider the health hazards and safety information contained herein as a guide and should take those precautions required in an individual operation to instruct employees and to develop work practice procedures for a safe work environment.

Abbreviations:

ACGIH: American Conference of Governmental & Industrial Hygienists.

OSHA: Occupational Safety & Health Administration

NIOSH: National Institute for Occupational Safety and Health

IARC: International Agency for Research on Cancer

NTP: National Toxicology Program

TLV: Threshold Limit Value (ACGIH)

PEL: Permissible Exposure Limit (OSHA)

TWA: Time Weighted Average

STEL: Short Term Exposure Limit

ppm: parts per million

mg/cum: milligrams per cubic meter of air

N/D: Not Determined

N/A: Not Applicable

HMIS: Hazardous Materials Identification System